However, they were found to harm the environment by thinning the ozone layer and were gradually banned by the united nations environment programme unep montreal protocol. Students are required to work in pairs and prepare a poster. Since the introduction of the montreal protocol, european consumption eea28 in 1986 has fallen from approximately 343 000 ozone. By 1985, the globe had already seen advancements in the scientific understanding of ozone depletion and its impacts on human health and the environment. When did we realize ozone depletion was an issue, and how did we fix it. Ozonaction united nations environment programme unep. Gratitude is expressed to uneps ozone secretariat, nairobi, kenya for the cooperation in formatting and styling of the report and for the reproduction of this report.
The regulations aim to improve containment of hfc refrigerants through leak testing, engineer qualification and record keeping. The following is a list of refrigerants with their typeprefix, ashrae designated numbers, iupac chemical name, molecular formula, cas registry number blend name, atmospheric lifetime in years, semiempirical ozone depletion potential, net global warming potential over a 100year time horizon, occupational exposure limitpermissible exposure. The zeroodp solution developed by dupont, r438a isceon mo99 is the ideal retrofit solution for many existing r22 systems across a wide range of applications, including low and mediumtemperature refrigeration equipment and air conditioning systems. Gratitude is expressed to uneps ozone secretariat, nairobi, kenya for the reproduction of this report. Update the unep customs training manual and the unepwco. It recognizes, however, that there is no onesizefitsall refrigerant solution.
Refrigerant regulatory evolution the global scrutiny on the gwp of all currentgeneration refrigerants continues to grow, pushing the. Since the introduction of the montreal protocol, european consumption eea28 in 1986 has fallen from approximately 343 000 ozonedepleting. This reduction has largely been driven by the 1987 united nations environment programme unep montreal protocol. It is intended for use by montreal protocol national ozone officers, customs and enforcement. National and regional regulations are coming into force around the world that will restrict the use of hfcs. The greatest concentration of ozone are found from 12 km to 50 km above the earth forming a layer in the stratosphere which is called the ozone layer. Chloroflourocarbons and their close cousins hcfcs are ozone layer depleting substances and. Ozonaction strengthens the capacity of governments particularly the operational focal points known as national ozone units and industry in developing countries to elaborate and enforce the policies. Refrigeration, air conditioning and heat pumps technical.
Unep ozone secretariat ozone secretariat unep bangkok, 20 and. Unep ozone secretariat ozone secretariat unep bangkok, 20. Unep ozone secretariat background material for hfc workshop, 2015 fact sheet 4. It breaks down and reacts with ozone molecules in accordance with the equation above repeatedly until a more stable compound is created. The refrigerants are expensive and have negative environmental impacts when released to the atmosphere. Odp ozone depletion potential degree to which a substance can degrade the ozone layer. Included are the internetdelivered training courses refrigerant literacy and sound management of refrigerants and a full semester universitylevel course on refrigerant technology. Hcfcs are ozone depleting substances, subject to worldwide production and consumption phase out schedules agreed under the international treaty known as the montreal protocol. Cfcs, hcfcs and hfcs are all part of a family of gases known as fgases or flourocarbons. Gwp global warming potential degree to which a greenhouse gas ghg traps heat in. Refrigerants transitioned first from toxic, flammable and unstable substances to safer ones in the form of cfcs and hcfcs.
It went into effect in 1987, first targeting cfcs, then hcfcs. Managing ozone depleting substances ods in refrigeration and airconditioning sector the development of the course, content and scholarly setup. R111, 2 global warming potential 100 year, ipcc 4th assessment report, 2007. Alternative refrigerants comprise more than 50% of the total market as it exists today. Global concern about depletion of the ozone layer resulted in the montreal protocol, an international treaty that established phaseout dates for the use and production of ozonedepleting substances.
Study on environmental and health effects of hfo refrigerants. Ashrae and united nations environment program unep have a dedicated web portal where jointly developed resources are available. Odss are used as refrigerants in refrigeration and airconditioning and heat pump systems. A molecule of regular oxygen can be converted to ozone by ultraviolet uv radiation, electrical discharge such as from lightning, or complex chemical reactions. Ever since the montreal protocol agreed to phase out hydrochlorofluorocarbons hcfcs, there has been an increasing interest within the protocol on climate issues. It protects us from harmful uv rays that can have serious effects on animals, biodiversity and peoples health, including skin cancer and eye cataract. Ozonaction fact sheet global warming potential gwp of refrigerants. Students are asked to write a conclusion comparing the different protocols and conventions, showing the most effective ones, and ending with the current global situation in regards of ods use. Environmental and safety considerations most commercially available refrigerants are safe for humans and working spaces.
Unlike regular oxygen, which contains two oxygen atoms o 2, ozone contains three oxygen atoms o 3. Production and consumption of ozonedepleting substances. Ozone is a gas naturally present in earths atmosphere. They absorb heat from one area, such as an airconditioned space, and reject it into another, such as outdoors, usually through evaporation and condensation. One way of reducing the amount of these refrigerants and the risk of leakage is to chill a secondary refrigerant, such as glycol or brine, in a centralized plant room and circulate this rather than the primary refrigerant.
When released to the atmosphere, those chemicals damage the stratospheric ozone layer, earths protective shield that. Ozone secretariat unep background material for hfc workshop, 2015 fact sheet 8. A significant reduction in the consumption of ozonedepleting substances ods has been achieved by the eea33 countries since 1986. Index 2 april 2015 fluid naming conventions for refrigerants there are many fluids referred to in these fact sheets. The opinions expressed are those of the committee and do not necessarily reflect the views of any sponsoring or supporting organisations. Refrigerant gases containing chlorine or bromine have a high ozone. Pdf stratospheric ozone, global warming, and the principle of. Linde strongly advocates the use of refrigerant gases with zero ozone depletion potential and fully supports the phase out of hcfcs.
Uneps compliance assistance programme multilateral fund. Experts blame ozonelayer depletion on manmade chem. Nonfluorinated refrigerants may provide comparable or superior performance to. Managing ozone depleting substances ods in refrigeration. Transitioning to lowgwp alternatives in residential and commercial air conditioning and chillers united nations environment programme unep. Unep, the teap cochairs and members, the refrigeration, ac and heat pumps technical options committee, cochairs and members, in furnishing or distributing this information, do not make any warranty or representation, either express or implied, with respect to the accuracy, completeness, or. Unep toc refrigeration, ac and heat pumps can be found in annex i.
Substance gwp time horizon years 2nd ipcc assessment report 1995 4th ipcc assessment report 2007 wmo 2010 5th ipcc assessment report 2014 wmo 2014 cfc12 20 7800 11 000. Gratitude is expressed to uneps ozone secretariat, nairobi, kenya for the cooperation in the last, final formatting and styling of the report, as well as for the reproduction of this 2018 rtoc assessment report. Lower gwp alternatives for small split airconditioning refrigerant gwp flammability2 comments hc290 hc1270 3. This section presents news and current information related to hcfcs. Policylegislation on fgases and alternatives two environmental frameworks one goal the montreal protocol and the kyoto protocol. Description of market sector this sector includes small split airconditioning units used for the cooling of single rooms in residential and commercial buildings.
Dec 20, 2019 a significant reduction in the consumption of ozonedepleting substances ods has been achieved by the eea33 countries since 1986. Distribution china accounted for 44% of global hcfc123 exports in 2016, followed by canada with 38% and. Natural refrigerants sustainable ozone and climatefriendly alternatives to hcfcs introduction dr. Department of mechani cal engineering, f ederal university of techn ology, akure, niger ia. In the case of refrigerants which are mixtures or blends of more than one refrigerant, the gwp is calculated as a massweighted average of the individual components. The main applications of hcfcs refrigerants are in commercial and industrial refrigeration, refrigerated transport, heat pumps, air conditioners and chillers. Refrigerants used in buildings and hvac equipment this article is intended an overview for architects, contractors and property owners on the subject of refrigerants used in hvac equipment. Gratitude is expressed to unep s ozone secretariat, nairobi, kenya for the cooperation in formatting and styling of the report and for the reproduction of this report. Decision xix6, taken in 2007, to adjust the protocol to accelerate the phase out of. According to the montreal protocol, the odp of refrigerants should be zero, i. The odp of blends are therefore calculated as follows. Projected emissions of hfo refrigerants hfo1234yf have also been calculated up to 2100 using bau and mit5 scenarios, with emissions of hfos and other lowgwp refrigerants expected to climb to 2050. Unepozonaction program is the custodian of the clearinghouse mandate for the montreal protocol with 9 active networks of ods officers in all developing countries. Production and consumption of ozonedepleting substances in.
Ozone depletion ozone depletion potential odp the higher the odp, the more damaging the chemical used for regulatory purposes by the united nations environment programme unep ultraviolet rays break off the chlorine atom of a cfc molecule the chlorine atom attaches itself to ozone and forms a chlorine monoxide. Introduction ever since the montreal protocol agreed to phase. Gwp refrigerants in a way that is technically feasible and allows for service. Students are asked to write a 2page report explaining more about the history of th i diti ithe air conditioning system. The regulatory control of fgases is split between the montreal protocol and the kyoto protocol.
These gases have to be eliminatednot just contained in 2004, the cocacola company, mcdonalds, and unilever with support from greenpeace and unep united nations environment program. Hcfcs are ozonedepleting substances, subject to worldwide production and consumption phase out schedules agreed under the international treaty known as the montreal protocol. A critical link in protecting climate and the ozone layer. It was then that the vienna convention for the protection of the ozone layer was created in response. Ashrae position document on refrigerants and their responsible use 5 a broad range of fluids has been used as refrigerant over the past century, and the current usage is dominated by a range of fluorinated chemicals, such as hfcs, in addition to hydro. Institutional strengthening, country programmes, refrigerant. A digital copy of this report can be downloaded at. United nations ep ozone secretariat conference portal.
Gratitude is expressed to unep s ozone secretariat, nairobi, kenya for the cooperation in the last, final formatting and styling of the report, as well as for the reproduction of this 2018 rtoc assessment report. However, they were found to harm the environment by thinning the ozone layer and were gradually banned by the united nations environment programme unep. Refrigerants having nonzero odp have either already been phasedout e. Published by the united nations environment programme unep. The unep ozone layer bulletins 1978 to 1985 recorded the. Introduction under the montreal protocol on substances that deplete the ozone layer, article 7 of the protocol requires all parties, both developing countries also called article 5 countries and developed countries. Global ozone protection, climate change and energy efficiency.
Transitioning to lowgwp alternatives in residential and. It is not intended to replace manufacturer guidelines or governmental advice which should be strictly adhered to. However, they have an impact on the environment by contributing to global warming andor ozone depletion. Substance gwp value 100 year substance gwp value 100 year hfcs hcfcs hfc4 1100 hcfc21 151 hfc4a 1430 hcfc22 1810. Commonly used nonods substitute refrigerants ashrae designation refrigerant type chemical name chemical formula gwp 100y1 ashrae safety group classification2 hs code3 2012 single component refrigerants r23 hfc trifluoromethane chf 3 14 800 a1 2903. Volkmar hasse, gtz proklima, germany preface volkmar hasse, gtz proklima i. Cfc replacements used as refrigerants, aerosol propellants. Ozone layer depletion odp and global warming potential gwp have become one of the most important global issues. Zero ozone depletion potential replacement for r22. They have substantially lower global warming potential than most fluorocarbons. Ozone depletion ozone is found in both the stratosphere and troposphere stratosphere is located 7 to 30 miles above the earth troposphere is located ground level to about 7 miles stratospheric ozone is considered good ozone, and acts as a shield by preventing excessive amounts of the suns ultraviolet rays from reaching the earth.
Ashrae is the largest society in the world with focus and mandate on refrigeration and airconditioning engineering sectors with 57,000 members and 211 chapters worldwide. That is, to calculate the odp of a blend, one simply adds the odps of the individual components in proportion to their mass. Executive summary, wmounep scientific assessment of ozone depletion. Commercial refrigeration 5 april 2015 condensing units a difficult subsector because the refrigerant charge is relatively high and flammability is an important. The videos provide useful guidance on safety and best practice, understanding the difference between different identifier units, testing procedures and identification of results.
United nations environment programme to sign the initial montreal protocol on substances that deplete the ozone layer. The military in many countries have been at the forefront of efforts to phaseout ozone depleting substances their experience can be invaluable for. Ashrae position document on refrigerants and their. Substance gwp time horizon years 2nd ipcc assessment report 1995 4th ipcc assessment report 2007 wmo 2010 5th ipcc assessment report 2014 wmo 2014 cfc12 20 7800 11 000 10 800 10 800. Environmental management of refrigeration equipment pdf, 151kb. The montreal protocol the montreal protocol on substances that deplete the ozone layer is the landmark multilateral environmental agreement that regulates the production and consumption of nearly 100 manmade chemicals referred to as ozone depleting substances ods. Alternatives to currently used hfc refrigerants table 2. The rightmost numeric value indicates the number of fluorine atoms, the next value to the. The montreal protocol unep, 1997 states the phasing out of cfcs and hcfcs as refrigerants that deplete the ozone layer.
Cfc11 and 12 are developed in the us, initially to be used as coolants for refrigeration. The unep refrigeration, ac and heat pumps technical options. What is ozone layer ozone is an isotope of oxygen with three atoms instead of normal two. Refrigerant management drawdown technical assessment references clodic, d. How to use unep dties ozonaction clearinghouse explains how the clearinghouse can support decision making in the selection of ozonefriendly technologies, products and policies.
Today, twenty five years later, the montreal protocol has been ratified by 197 countries, making it the first treaty of any kind to have achieved universal rati fication. Refrigerants are regulated as hazardous materials by the us epa and carb, due to their ozone depleting ability and powerful greenhouse gas potential. Ashrae position document on refrigerants and their responsible use 2 executive summary refrigerants are the working fluids in refrigeration, airconditioning, and heatpumping systems. It is naturally occurring gas which is created by high energy radiation from the sun. Refrigerants containing chlorine or bromine contribute to the breakdown of the ozone layer see figure 5.
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